catena -Poly[[manganese(II)-tris(μ-betaine-κ 2 O : O ′)] tetrabromidomanganate(IV)

The title compound, [Mn(C5H11NO2)3]·MnBr4, contains polymeric cationic chains of distorted MnO6 octahedra and bridging betaine molecules, running parallel to the a axis. There are two distinct Mn2+ cations in the chain, both with site symmetry overline{1}. Distorted [MnBr4]2− tetrahedra occupy the s...

Full description

Saved in:
Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 64; no. 10; pp. m1273 - m1274
Main Authors Kocadag, Maria, Fleck, Michel, Bohatý, Ladislav
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.10.2008
Online AccessGet full text

Cover

More Information
Summary:The title compound, [Mn(C5H11NO2)3]·MnBr4, contains polymeric cationic chains of distorted MnO6 octahedra and bridging betaine molecules, running parallel to the a axis. There are two distinct Mn2+ cations in the chain, both with site symmetry overline{1}. Distorted [MnBr4]2− tetrahedra occupy the spaces between the chains.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808028912