Selective Removal of Benzyl Carbonate Used as a Protecting Group in Carbohydrate Chemistry

It has been demonstrated that benzyl carbonate protecting group is orthogonal with tert-butyldimethylsilyl and (4-methoxy)trityl ethers. Moreover, benzyl carbonates can be selectively cleaved using aminolysis conditions.

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Bibliographic Details
Published inSynthetic communications Vol. 34; no. 2; pp. 303 - 307
Main Authors Mouffouk, Fouzi, Morère, Alain, Vidal, Sébastien, Leydet, Alain, Montero, Jean-Louis
Format Journal Article
LanguageEnglish
Published Taylor & Francis Group 01.01.2004
Subjects
Benzyloxycarbonyl
Carbohydrate
Carbonate
Deprotection
Selective
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Summary:It has been demonstrated that benzyl carbonate protecting group is orthogonal with tert-butyldimethylsilyl and (4-methoxy)trityl ethers. Moreover, benzyl carbonates can be selectively cleaved using aminolysis conditions.
ISSN:0039-7911
1532-2432
DOI:10.1081/SCC-120027267