Grain boundary segregation and its implications regarding the formation of the grain boundary α phase in the metastable β-Titanium Ti–5Al–5Mo–5V–3Cr alloy
We investigated the origin of the deleterious grain boundary α phase formed during the aging of the β-titanium alloy, Ti–5Al–5Mo–5V–3Cr–0.5Fe (wt.%). We probed the composition of low and high-angle grain boundaries from the as-quenched β condition correlating electron microscopy and atom probe tomog...
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Published in | Scripta materialia Vol. 207; p. 114320 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier Ltd
15.01.2022
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Subjects | |
Online Access | Get full text |
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Summary: | We investigated the origin of the deleterious grain boundary α phase formed during the aging of the β-titanium alloy, Ti–5Al–5Mo–5V–3Cr–0.5Fe (wt.%). We probed the composition of low and high-angle grain boundaries from the as-quenched β condition correlating electron microscopy and atom probe tomography. Our analysis reveals strong segregation of some α-stabilizing elements at both types of boundaries, especially oxygen, along with a depletion of β-stabilizing elements. The grain boundary maintains the body-centered-cubic structure despite the presence of this local composition. Our thermodynamic calculations, based on the measured grain boundary compositions, indicate that the segregation significantly increases the chemical driving force for α nucleation upon aging. Our work provides essential insight into the formation of the undesired grain boundary α layers along prior-β grain boundaries in metastable β-Ti alloys and paves the way for microstructural engineering of these alloys with enhanced mechanical properties.
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ISSN: | 1359-6462 1872-8456 |
DOI: | 10.1016/j.scriptamat.2021.114320 |