A tetranuclear molecular rectangle from four gold(I) atoms linked by dicarbene and diphosphine ligands

A tetranuclear molecular rectangle consisting of two bridging dicarbene ligands and two bridging diphosphine ligands was prepared by connection of two dinuclear gold(I) complexes with 1,2-bis(diphenylphosphino)ethane.

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Bibliographic Details
Published inDalton transactions : an international journal of inorganic chemistry no. 43; pp. 9392 - 9394
Main Authors Radloff, Christian, Weigand, Jan J, Hahn, F Ekkehardt
Format Journal Article
LanguageEnglish
Published England 01.01.2009
Subjects
Gold - chemistry
Ligands
Magnetic Resonance Spectroscopy
Methane - analogs & derivatives
Methane - chemistry
Organometallic Compounds - chemistry
Phosphines - chemistry
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Summary:A tetranuclear molecular rectangle consisting of two bridging dicarbene ligands and two bridging diphosphine ligands was prepared by connection of two dinuclear gold(I) complexes with 1,2-bis(diphenylphosphino)ethane.
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ISSN:1477-9226
1477-9234
DOI:10.1039/b916651c