Flavonoids and Triterpenoid Saponins from Pimenta dioica (Merr.) L
The defatted and desalted 80% methanolic extract of the leaves of Pimenta dioica (Mirr.) L. resulted in the isolation of three triterpenoid saponins, 23-hydroxy-3α-[(O-α-L-rhamnopyranosyl-(1→2)-O-α-L-arabinopyranosyl) oxy] olean-12-en-28-oic acid O-α-L-rhamnopyranosyl-(1→4)-O-β-D-galactopyranosyl-(1...
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Published in | Natural product communications Vol. 2; no. 9; p. 1934578 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Los Angeles, CA
SAGE Publications
01.09.2007
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Subjects | |
Online Access | Get full text |
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Summary: | The defatted and desalted 80% methanolic extract of the leaves of Pimenta dioica (Mirr.) L. resulted in the isolation of three triterpenoid saponins, 23-hydroxy-3α-[(O-α-L-rhamnopyranosyl-(1→2)-O-α-L-arabinopyranosyl) oxy] olean-12-en-28-oic acid O-α-L-rhamnopyranosyl-(1→4)-O-β-D-galactopyranosyl-(1→6)-O-β-D-galactopyranosyl ester (1), 2α,3α,23-trihydroxyolean-12-en-28-oic acid O-β-D-glucopyranosyl ester (2), and 2α,3α,23-trihydroxyolean-13(18)-en-28-oic acid O-β-D-glucopyranosyl ester (3), along with a novel dihydrokaempferol glucoside, namely, 3-carboxy-6,8-di-C-methyl-dihydrokaempferol 3-O-β-D-glucopyranoside (4), together with three known flavonoids, quercetin 3-O-β-D-glucuronopyranoside (5), quercitrin (6) and mernesitin (7), all for the first time from the genus Pimenta. The structures were identified on the basis of chemical and physicochemical analysis (UV, HRESI-MS, 1 and 2D NMR). |
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ISSN: | 1934-578X 1555-9475 |
DOI: | 10.1177/1934578X0700200904 |