Synthesis, Crystal Structure and Magnetism Characterization of Two Coordination Polymers based on Ni(2-mpac)2(H2O)2 as Molecular Building Block

Taking Ni(2‐mpac)2(H2O)2 as molecular building block, two novel coordination polymers with the formula of [Ni(2‐mpac)2(4,4′‐bpy)·(4,4′‐bpy)]n (1) and [Ni(2‐mpac)2(py)·4H2O]n (2) (2‐mpac = 5‐methyl‐2‐pyrazinecarboxylic acid; 4,4′‐bpy = 4,4′‐bipyridine; py = pyrazine) have been synthesized and structu...

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Published inZeitschrift für anorganische und allgemeine Chemie (1950) Vol. 634; no. 3; pp. 539 - 544
Main Authors Chen, San-Ping, Fan, Guang, Gao, Sheng-Li
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.03.2008
WILEY‐VCH Verlag
Subjects
Coordinationpolymers
Magnetic properties
Molecular building block
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Summary:Taking Ni(2‐mpac)2(H2O)2 as molecular building block, two novel coordination polymers with the formula of [Ni(2‐mpac)2(4,4′‐bpy)·(4,4′‐bpy)]n (1) and [Ni(2‐mpac)2(py)·4H2O]n (2) (2‐mpac = 5‐methyl‐2‐pyrazinecarboxylic acid; 4,4′‐bpy = 4,4′‐bipyridine; py = pyrazine) have been synthesized and structurally characterized by X‐ray single crystal diffraction method. In addition, elemental analysis, IR and magnetism characterization are presented.
Bibliography:istex:CB2927837619A925BA77AAE53A760D3B81B40D6D
ark:/67375/WNG-XSJVL31M-1
ArticleID:ZAAC200700441
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200700441