The first rare earth organometallic complex of 1,4,7-trithiacyclononane: a precursor to unique cationic ethylene and alpha-olefin polymerisation catalysts supported by an all-sulfur donor ligand
[Sc([9]aneS(3))(CH2SiMe3)(3)], the first rare earth organometallic complex of 1,4,7-trithiacyclonane, is a precursor to ethylene and alpha-olefin polymerisation catalysts upon activation with BAr3F or [CPh3][BAr4F] (Ar-F = C6F5); these are the first cationic rare earth organometallic catalysts suppo...
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Published in | Chemical communications (Cambridge, England) no. 26; pp. 3301 - 3303 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
CAMBRIDGE
Royal Soc Chemistry
14.07.2005
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Subjects | |
Online Access | Get more information |
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Summary: | [Sc([9]aneS(3))(CH2SiMe3)(3)], the first rare earth organometallic complex of 1,4,7-trithiacyclonane, is a precursor to ethylene and alpha-olefin polymerisation catalysts upon activation with BAr3F or [CPh3][BAr4F] (Ar-F = C6F5); these are the first cationic rare earth organometallic catalysts supported by an all-sulfur donor ligand. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/b503967c |