The first rare earth organometallic complex of 1,4,7-trithiacyclononane: a precursor to unique cationic ethylene and alpha-olefin polymerisation catalysts supported by an all-sulfur donor ligand

[Sc([9]aneS(3))(CH2SiMe3)(3)], the first rare earth organometallic complex of 1,4,7-trithiacyclonane, is a precursor to ethylene and alpha-olefin polymerisation catalysts upon activation with BAr3F or [CPh3][BAr4F] (Ar-F = C6F5); these are the first cationic rare earth organometallic catalysts suppo...

Full description

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) no. 26; pp. 3301 - 3303
Main Authors Tredget, CS, Bonnet, F, Cowley, AR, Mountford, P
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 14.07.2005
Subjects
Online AccessGet more information

Cover

Loading…
More Information
Summary:[Sc([9]aneS(3))(CH2SiMe3)(3)], the first rare earth organometallic complex of 1,4,7-trithiacyclonane, is a precursor to ethylene and alpha-olefin polymerisation catalysts upon activation with BAr3F or [CPh3][BAr4F] (Ar-F = C6F5); these are the first cationic rare earth organometallic catalysts supported by an all-sulfur donor ligand.
ISSN:1359-7345
1364-548X
DOI:10.1039/b503967c