Light-fluorous safety-catch arylgermanes - exceptionally robust, photochemically activated precursors for biaryl synthesis by Pd(0) catalysed cross-coupling

A new class of arylgermane derivative that participate efficiently in Pd(0)-catalysed cross-coupling reactions with aryl bromides following photochemical activation is described.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 28; pp. 2926 - 2928
Main Authors Spivey, Alan C., Tseng, Chih-Chung, Hannah, Joseph P., Gripton, Christopher J. G., de Fraine, Paul, Parr, Nigel J., Scicinski, Jan J.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2007
Subjects
Biphenyl Compounds - chemical synthesis
Catalysis
Chemistry
Chemistry, Multidisciplinary
Cross-Linking Reagents - chemistry
Germanium - chemistry
Organic Chemicals - chemical synthesis
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Palladium - chemistry
Photochemistry
Physical Sciences
Science & Technology
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Summary:A new class of arylgermane derivative that participate efficiently in Pd(0)-catalysed cross-coupling reactions with aryl bromides following photochemical activation is described.
ISSN:1359-7345
1364-548X
DOI:10.1039/b707517k