Latest progress in asymmetrically functionalized Anderson-type polyoxometalates
Anderson-type polyoxometalates (POMs) are one of the most important and widely developed groups of the POM family. The covalent functionalization of Anderson POMs has attracted extensive attention and facilitated broad applications of the resultant POM hybrids in catalysis, biology, energy materials...
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| Published in | Inorganic chemistry frontiers Vol. 1; no. 6; pp. 1695 - 1711 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Royal Society of Chemistry
14.03.2023
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| Subjects | |
| Online Access | Get full text |
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| Summary: | Anderson-type polyoxometalates (POMs) are one of the most important and widely developed groups of the POM family. The covalent functionalization of Anderson POMs has attracted extensive attention and facilitated broad applications of the resultant POM hybrids in catalysis, biology, energy materials and medicine. Among the various synthetic methods for Anderson hybrids, asymmetric functionalization has been one of the hottest and unique topics in the last decade. In the structure of asymmetric Anderson hybrids, two different organic components are anchored onto each side of the Anderson cluster or only one side of the cluster is functionalized. Asymmetric functionalization provides complexity to POM assemblies and merges multiple functions into one hybrid molecule, meanwhile, bringing challenges of rational design and controllable synthetic strategies. In this review, the latest progress in the synthetic methods and applications of asymmetrically functionalized Anderson-type POMs is summarized according to the central heteroatom of the cluster, which includes Mn-, Cr-, Al- and other metal-templated Anderson POMs.
Asymmetrically functionalized Anderson-type polyoxometalates were overviewed, including the key factors of various synthesis methods, separation methods, advantages of asymmetric structures, and their applications. |
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| Bibliography: | Zeqian Sun is currently a master's degree candidate in Prof. Yu-Fei Song's group at the State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology. His current research interest is the structural design and application of covalently modified polyoxometalates. Bo Qi received his bachelor's and PhD degrees in chemistry from Dalian University of Technology (supervisor: Prof. Chunying Duan). In 2015, he worked as a visiting scholar at the University of Akron (supervisor: Prof. Tianbo Liu). In 2018, he joined Prof. Yu-Fei Song's group at Beijing University of Chemical Technology. His research interests include self-assembly and heterogeneous chiral/electro/photo catalysis in polyoxometalate chemistry. Energy. Environ. Sci. Dr Yu-Fei Song received his BS (1997) and PhD (2002) degrees from Shanxi University. After postdoc research in Leiden University, the Max-Planck Institute of Bio-inorganic Chemistry, and the University of Glasgow, he joined Beijing University of Chemical Technology (BUCT) in 2008. He is currently holding a full professor position in BUCT. His research directions mainly focus on polyoxometalate-based molecular assemblies and multifunctional materials. He has published over 280 research papers in journals such as Soc Qinghe Zhuang received his bachelor's degree from Beijing University of Chemical Technology in 2020. He is currently a master's degree candidate in Prof. Yu-Fei Song's group at the State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology. His research interests are the design and synthesis of new polyoxometalates. Nat. Commun. J Angew , Am Chem Nat. Protoc. . Int Chang-Gen Lin received his BS degree from Beijing University of Chemical Technology (BUCT) in 2010, and completed his PhD under the supervision of Prof. Yu-Fei Song at the same university in 2015. After a two-year postdoc at BAIC-SM, he was appointed as a lecturer at BUCT. In 2019, he was awarded a CSC scholarship to work with Prof. Leroy Cronin at the University of Glasgow on 3D printing and automated chemical synthesis. One year later he returned to BUCT, where he is now an associate professor of chemistry. His research interests include supramolecular self-assembly, organic-inorganic polyoxometalate hybrids, and photo-/electro-responsive materials. etc. He was awarded "National Science Foundation for Distinguished Young Scholars of China" (2016). Ed |
| ISSN: | 2052-1553 2052-1545 2052-1553 |
| DOI: | 10.1039/d2qi02690b |