Nanostructured columnar heterostructures of TiO2 and Cu2O enabled by a thin-film self-assembly approach: Potential for photovoltaics

• Published in: Materials research bulletin Vol. 48; no. 2; pp. 352 - 356
• Main Authors: Polat, Özgür, Aytug, Tolga, Lupini, Andrew R., Paranthaman, Parans M., Ertugrul, Mehmet, Bogorin, Daniela F., Meyer, Harry M., Wang, Wei, Pennycook, Stephen J., Christen, David K.
• Format: Journal Article
• Language: English
• Published: United States Elsevier Ltd 01.02.2013
• Subjects: A. Nanostructures; A. Thin films; B. Epitaxial growth; B. Sputtering; D. Microstructure; D. Microstructure; A. Nanostructures; A. Thin films; B. Sputtering; B. Epitaxial growth
• ISSN: 0025-5408; 1873-4227
• DOI: 10.1016/j.materresbull.2012.10.044

[Display omitted] ► Material self-assembly in phase-separated oxides is exploited. ► Three-dimensionally nanostructured epitaxial films are grown using sputtering. ► Films are composed of well-ordered oriented nanopillars of n-type TiO2 and p-type Cu2O. ► Observed interfaces at adjacent TiO2–Cu2O columns are nearly atomically distinct. ► Absorption profile of the composite film captures a wide range of the solar spectrum. Significant efforts are being devoted to the development of multifunctional thin-film heterostructures and nanostructured material architectures for components with novel applications of superconductivity, multiferroicity, solar photocatalysis and energy conversion. In particular, nanostructured assemblies with well-defined geometrical shapes have emerged as possible high efficiency and economically viable alternatives to planar photovoltaic thin-film architectures. By exploiting phase-separated self-assembly, here we present advances in a vertically oriented two-component system that offers potential for future development of nanostructured thin film solar cells. Through a single-step deposition by magnetron sputtering, we demonstrate growth of an epitaxial, composite film matrix formed as self-assembled, well ordered, phase segregated, and oriented nanopillars of n-type TiO2 and p-type Cu2O. The composite films were structurally characterized to atomic resolution by a variety of analytical tools, and evaluated for preliminary optical properties using absorption measurements. We find nearly atomically distinct TiO2–Cu2O interfaces (i.e., needed for possible active p–n junctions), and an absorption profile that captures a wide range of the solar spectrum extending from ultraviolet to visible wavelengths. This high-quality materials system could lead to photovoltaic devices that can be optimized for both incident light absorption and carrier collection.