A geometric switching approach toward thermal activation of metalloenediynes

Tetradentate metalloenediynes with strong imine and weaker thioether coordination serve as a geometrically non-rigid switch to drive thermal Bergman cyclization.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 42; pp. 5295 - 5297
Main Authors Bhattacharyya, S, Dye, DF, Pink, M, Zaleski, JM
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 14.11.2005
Subjects
Chemistry
Chemistry, Multidisciplinary
Cyclization
Enediynes - chemistry
Hot Temperature
Metals - chemistry
Models, Molecular
Molecular Structure
Physical Sciences
Science & Technology
MOLECULAR CALCULATIONS
EFFECTIVE CORE POTENTIALS
PYRIDINE
CU(II)
ZN(II)
REACTIVITY
ATOMS
LIGAND
BERGMAN CYCLIZATION
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Summary:Tetradentate metalloenediynes with strong imine and weaker thioether coordination serve as a geometrically non-rigid switch to drive thermal Bergman cyclization.
Bibliography:Medline
NIH RePORTER
ISSN:1359-7345
1364-548X
DOI:10.1039/b509125j