Synthesis of Tröger's base-based [3]arenes for efficient iodine adsorption

Enantiomers of Tröger's base-based [3]arenes R 6N - E[3] and S 6N - E[3] were synthesized successfully as two optically pure Tröger's base-based macrocycles in which three Tröger's base subunits were incorporated. Among these Tröger's base-based[3]arenes, M[3] showed high absorpt...

Full description

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 59; no. 73; pp. 196 - 1963
Main Authors Niu, Pengbo, Shi, Conghao, Jiao, Jianmin, Xie, Wang, Qiu, Heng, Yang, Zhen, Jiang, Juli, Wang, Leyong
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 12.09.2023
Royal Society of Chemistry
Subjects
Aromatic compounds
Chemistry
Chemistry, Multidisciplinary
Enantiomers
Iodine
Physical Sciences
Science & Technology
CAPTURE
Online AccessGet full text

Cover

More Information
Summary:Enantiomers of Tröger's base-based [3]arenes R 6N - E[3] and S 6N - E[3] were synthesized successfully as two optically pure Tröger's base-based macrocycles in which three Tröger's base subunits were incorporated. Among these Tröger's base-based[3]arenes, M[3] showed high absorption of iodine up to 4.02 g g −1 in vapor. Enantiomers of Tröger's base-based [3]arenes R 6N - E[3] and S 6N - E[3] were synthesized successfully as two optically pure Tröger's base-based macrocycles in which three Tröger's base subunits were incorporated.
Bibliography:CCDC
2224433
For ESI and crystallographic data in CIF or other electronic format see DOI
Electronic supplementary information (ESI) available: Experimental data, NMR spectra
https://doi.org/10.1039/d3cc02804f
etc.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc02804f