Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

Palladium-catalyzed regioselective electrocarboxylation of homostyrenyl acetates with CO2 has been successfully developed, providing -aryl carboxylic acids with good selectivity and yield. In addition, the catalytic asymmetric carboxylation of cinnamyl acetate has been demonstrated, despite moderate...

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Published inORGANIC CHEMISTRY FRONTIERS Vol. 5; no. 14; pp. 2244 - 2248
Main Authors Jiao, Ke-Jin, Li, Zhao-Ming, Xu, Xue-Tao, Zhang, Li-Pu, Li, Yi-Qian, Zhang, Kun, Mei, Tian-Sheng
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.07.2018
Royal Society of Chemistry
Subjects
Acetates
Acetic acid
Aromatic compounds
Carbon dioxide
Carboxylation
Carboxylic acids
Catalysis
Chemistry
Chemistry, Organic
Enantiomers
Esters
Organic chemistry
Palladium
Physical Sciences
Science & Technology
HALIDES
VISIBLE-LIGHT
NICKEL
COUPLING REACTIONS
LIGHT-DRIVEN CARBOXYLATION
UNSATURATED-HYDROCARBONS
CO2
METAL
ARYL
BUILDING-BLOCK
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Summary:Palladium-catalyzed regioselective electrocarboxylation of homostyrenyl acetates with CO2 has been successfully developed, providing -aryl carboxylic acids with good selectivity and yield. In addition, the catalytic asymmetric carboxylation of cinnamyl acetate has been demonstrated, despite moderate enantioselectivity.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:2052-4129
2052-4110
2052-4110
DOI:10.1039/c8qo00507a