Chlorodifluoromethyl phenyl sulfone: a novel non-ozone-depleting substance-based difluorocarbene reagent for O- and N-difluoromethylations

Chlorodifluoromethyl phenyl sulfone, a previously unknown compound that can be readily prepared from non-ODS-based precursors, was found to act as a robust difluorocarbene reagent for O- and N-difluoromethylations.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 48; pp. 5149 - 5151
Main Authors Zheng, Ji, Li, Ya, Zhang, Laijun, Hu, Jinbo, Meuzelaar, Gerrit Joost, Federsel, Hans-Juergen
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2007
Subjects
Chemistry
Chemistry, Multidisciplinary
Hydrocarbons, Fluorinated - chemical synthesis
Hydrocarbons, Fluorinated - chemistry
Hydrocarbons, Halogenated - chemical synthesis
Hydrocarbons, Halogenated - chemistry
Methylation
Molecular Structure
Physical Sciences
Science & Technology
Stereoisomerism
Sulfones - chemical synthesis
Sulfones - chemistry
NUCLEOPHILIC TRIFLUOROMETHYLATION
ALDEHYDES
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Summary:Chlorodifluoromethyl phenyl sulfone, a previously unknown compound that can be readily prepared from non-ODS-based precursors, was found to act as a robust difluorocarbene reagent for O- and N-difluoromethylations.
ISSN:1359-7345
1364-548X
DOI:10.1039/b713156a