The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding

This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol （described as FcCH2OH） molecular clusters. The enhanced electronic communication in FcCH2OH clusters is confirmed and further investigated by differential-pu...

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Bibliographic Details
Published inChinese chemical letters Vol. 29; no. 1; pp. 179 - 182
Main Authors Yang, Yifan, Zheng, Qing, Yan, Yuanyuan, Liu, Yao, Shao, Huibo
Format Journal Article
LanguageEnglish
Published Elsevier B.V 2018
Subjects
Cyclic voltammetry
Electron transfer
Enhanced electronic communication
Intermolecular hydrogen-bonding
Molecular clusters
Enhanced electronic communication
Cyclic voltammetry
Electron transfer
Molecular clusters
Intermolecular hydrogen-bonding
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Summary:This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol （described as FcCH2OH） molecular clusters. The enhanced electronic communication in FcCH2OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivariv~ which it ha~pd nn rhp inr~rmnlpcldar hvdrn~en-hnndinct
Bibliography:11-2710/O6
This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol （described as FcCH2OH） molecular clusters. The enhanced electronic communication in FcCH2OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivariv~ which it ha~pd nn rhp inr~rmnlpcldar hvdrn~en-hnndinct
Enhanced electronic communicationlntermolecular hydrogen-bondingMolecular clustersElectron transferCyclic voltammetry
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2017.06.011