Electrical Conductivity of Ni-YSZ Anode for SOFCs According to the Ni Powder Size Variations in Core-shell Structure

• Published in: Korean Journal of Metals and Materials Vol. 53; no. 4; pp. 287 - 293
• Main Authors: Choi, Byung-Hyun, Kang, Young Jin, Jung, Sung-Hun, An, Yong-Tae, Ji, Mi-Jung
• Format: Journal Article
• Language: English
• Published: 대한금속·재료학회 01.04.2015
• Subjects: 재료공학
• ISSN: 1738-8228; 2288-8241
• DOI: 10.3365/KJMM.2015.53.4.287

Ni-YSZ (Y2O3-stabilized ZrO2) core-shell structures were prepared by a high-speed mixing method, starting from Ni particles of three different average sizes of 0.2, 0.4, and 1.8 μm. The Ni-YSZ core-shell structures prepared using Ni particles of size 0.2, 0.4, and 1.8 μm exhibited dense core, porous core, and random-morphology core, respectively. Subsequently, nanostructured cermet anodes were fabricated using the prepared Ni-YSZ core-shell powders. During the formation of cermet, the heat treatment of Ni-YSZ core-shell powder results in the eruption of Ni core out of the YSZ shell layers, thereby facilitating the formation of nanostructured Ni-YSZ cermet. Systematic studies indicated that the morphology and electrical conductivity of the prepared Ni-YSZ core-shell powders and the cermet anode varied, depending on the initial particle size of the Ni particles. Of the different samples prepared in this study, the Ni-YSZ cermet prepared using Ni particles of size 0.4 μm showed the highest electrical conductivity at 750 ℃. KCI Citation Count: 5