Preparation of chiral triarylphosphines by Pd-catalysed asymmetric P-C cross-coupling

Enantioselective C-P cross-coupling of diarylphosphines and ortho-substituted aryl iodides has been achieved with >90%ee, using an in situ catalyst prepared from Et,Et-FerroTANE, Pd-2(dba)(3)xCHCl(3) and LiBr.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 5; pp. 530 - 531
Main Authors Korff, C, Helmchen, G
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 07.03.2004
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
PHOSPHORUS
PAMP-BH3
HYDROGENATION
ENANTIOSELECTIVE SYNTHESIS
LIGANDS
STEREOCHEMISTRY
BORANES
DERIVATIVES
CHIROGENIC PHOSPHINE
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Summary:Enantioselective C-P cross-coupling of diarylphosphines and ortho-substituted aryl iodides has been achieved with >90%ee, using an in situ catalyst prepared from Et,Et-FerroTANE, Pd-2(dba)(3)xCHCl(3) and LiBr.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/b315009g