Compound layer growth and compound layer porosity of austenite plasma nitrocarburised non-alloyed steel

• Published in: Surface & coatings technology Vol. 71; no. 2; pp. 112 - 120
• Main Authors: Li, Shi, Manory, Rafael R., Hensler, John H.
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Lausanne Elsevier B.V 01.03.1995; Elsevier
• Subjects: Applied sciences; Exact sciences and technology; Heat treatment; Low carbon steel; Metals. Metallurgy; Plasma nitrocarburising; Porosity of compound layer; Production techniques; Thermochemical treatment and diffusion treatment; ε-Carbonitride; Plasma nitrocarburising; Low carbon steel; ε-Carbonitride; Porosity of compound layer; Methane; Thermochemical treatment; Heat treatment; Hydrogen; Metallography; Nitriding; Etching reagent; Nitrogen; Experimental study; Epsilon phase; X ray diffraction; Surface treatment; Carbides nitrides; Porosity; Diffusion; Microstructure; Ion nitriding
• ISSN: 0257-8972; 1879-3347
• DOI: 10.1016/0257-8972(94)01009-8

Compound layer growth and compound layer porosity of an austenite plasma nitrocarburised slowly cooled AISI 1020 steel sample were studied by controlling the plasma nitrocarburising atmosphere with nitrogen, hydrogen and methane content in the following proportions: 25 vol.% N 2, 73.25 vol.% H 2, 1.75 vol.% CH 4 at 600 °C. During the iniial stage of plasma nitrocarburising, highly porous surface structures are formed similar to those described as “the open structure of a piece of coral” observed in salt bath nitrocarburising. For a 9 min treated sample a triple layer composed of cementile, compound layer and nitrogen austenite is formed, which further develops into ε iron nitride containing a compound layer and the dissociated nitrogen austenite sublayer. Porosity is mainly nucleated and grows at the grain boundaries, the carbon-enriched region and places where α-iron forms. The structures of quenched and annealed samples were also examined. Pure ε compound top layer can be retained after quenching. This layer is unstable at this gas composition and transforms to γ′, α-iron (and Fe 3C) containing ε during slow cooling. Annealing enhances the core property of the plain carbon steel by transforming the martensite and residual nitrogen austenite into bainite.