[PtMe(iPr3P)2]+: a Pt(II) complex with an agostic interaction that undergoes C-H activation

The T-shaped Pt(II) complex [PtMe(iPr3P)2][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11].

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 21; pp. 2398 - 2399
Main Authors Ingleson, Michael J, Mahon, Mary F, Weller, Andrew S
Format Journal Article
LanguageEnglish
Published England 07.11.2004
Subjects
Acids - chemistry
Catalysis
Crystallography, X-Ray
Models, Molecular
Molecular Structure
Organometallic Compounds - chemistry
Platinum - chemistry
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Summary:The T-shaped Pt(II) complex [PtMe(iPr3P)2][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11].
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/b410846a