Mild catalytic oxidation of secondary and tertiary amines to nitrones and N-oxides with H2O2 mediated by Pt(ii) catalysts

Bridging hydroxo complexes of Pt(ii) can be used as catalysts for the oxidation of tertiary and secondary amines under mild conditions using the environmentally benign hydrogen peroxide as the oxidant. The reaction proceeds with medium to excellent yields particularly in the case of the more electro...

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Published inGreen chemistry : an international journal and green chemistry resource : GC Vol. 10; no. 7; pp. 793 - 798
Main Authors Colladon, Marco, Scarso, Alessandro, Strukul, Giorgio
Format Journal Article
LanguageEnglish
Published 01.01.2008
Subjects
Amines
Catalysts
green development
hydrogen peroxide
Oxidants
Oxidation
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Summary:Bridging hydroxo complexes of Pt(ii) can be used as catalysts for the oxidation of tertiary and secondary amines under mild conditions using the environmentally benign hydrogen peroxide as the oxidant. The reaction proceeds with medium to excellent yields particularly in the case of the more electron rich tertiary amines.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:1463-9262
1463-9270
DOI:10.1039/b805404e