Two New Rb3Sc(IO3)6 Polytypes in Proposed Nonlinear Optical Family A3M(IO3)6 (A = K, Rb; M = Sc, In): Topology–Symmetry Analysis, Order–Disorder and Structure–Properties Relation

• Published in: Symmetry (Basel) Vol. 14; no. 8; p. 1699
• Main Authors: Reutova, Olga, Belokoneva, Elena, Volkov, Anatoly, Dimitrova, Olga, Stefanovich, Sergey
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.08.2022
• Subjects: Crystal growth; Crystal structure; Experiments; Grain size; Habitus; hydrothermal synthesis; iodates; nonlinear optical properties; Nonlinear optics; Nonlinearity; order–disorder; Polytypes; Single crystals; single-crystal X-ray diffraction; Symmetry; Topology; topology–symmetry analysis
• ISSN: 2073-8994; 2073-8994
• DOI: 10.3390/sym14081699

Two polytypic modifications of new non-centrosymmetric iodate Rb3Sc(IO3)6 are synthesized hydrothermally. Their structures demonstrate different degrees of ordering and are solved in the same space group, Pc, with differing choice of b-axis: either 20 or 40 Å is selected from the same diffraction data, measured on crystals with better ordering. The difference in NLO properties of two polytypes is disclosed. Topology–symmetry analysis of separated blocks and layers allowed determination of local symmetry corresponding to mirror plane m, which defines strong optical nonlinearity. Layer alternation indicates a polytypic nature of Rb, Sc-iodate and its similarity to K, In- and K, Sc-nonlinear-optical iodate crystals, space group Fdd2, belonging to the proposed common family A3M(IO3)6 (A = K, Rb; M = Sc, In), whose properties are explained on a symmetry basis for every known member. Hypothetical structural variant is predicted; structural disorder and crystal growth conditions are discussed as factors affecting properties.