TG-DSC-FTIR Analysis of Cyanobacteria Pyrolysis

Pyrolysis of cyanobacteria from Dianchi lake was investigated by TG-DSC-FTIR analysis at different heating rates (10, 20, 40°C/min). The results indicated that the pyrolysis of cyanobacteria can be divided into four stages: evaporation, depolymerization, devolatilization and carbonization. Meanwhile...

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Bibliographic Details
Published inPhysics procedia Vol. 33; pp. 657 - 662
Main Authors Supeng, Luo, Guirong, Bao, Hua, Wang, Fashe, Li, Yizhe, Li
Format Journal Article
LanguageEnglish
Published Elsevier B.V 2012
Subjects
cyanobacteria ;TG-FTIR analysis ;pyrolysis characteristics ;kinetic ;Popescu method
cyanobacteria ;TG-FTIR analysis ;pyrolysis characteristics ;kinetic ;Popescu method
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Summary:Pyrolysis of cyanobacteria from Dianchi lake was investigated by TG-DSC-FTIR analysis at different heating rates (10, 20, 40°C/min). The results indicated that the pyrolysis of cyanobacteria can be divided into four stages: evaporation, depolymerization, devolatilization and carbonization. Meanwhile, the initial weight-loss temperature, weight-loss extreme position, endothermic and exothermic peaks were moved to higher temperature with the increaseing of the heating rate. The kinetic analysis was made with Popescu method. It indicated that the best kinetic model for the pyrolysis of cyanobacteria was the cylindrical symmetry of the phase boundary reaction model. The main pyrolysis gases checked with real-time online FTIR were HCN, NH3, CO, CO2, water vapor and hydrocarbons.
ISSN:1875-3892
1875-3892
DOI:10.1016/j.phpro.2012.05.117