Cobalt-catalyzed synthesis of tertiary azides from alpha,alpha-disubstituted olefins under mild conditions using commercially available reagents

The use of commercially available azide sources is presented for the cobalt-catalyzed hydroazidation reaction alpha,alpha-Disubstituted olefins with a variety of functional groups were employed as substrates, providing tertiary azides in useful yields.

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Bibliographic Details
Published inSynthesis (Stuttgart) no. 24; pp. 3839 - 3845
Main Authors Gaspar, Boris, Waser, Jerome, Carreira, Erick M.
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 17.12.2007
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
HYDRAZOIC ACID
TETRAZOLES
ENOL ETHERS
CONVERSION
hydroazidation
silanes
cobalt
alkenes
ALCOHOLS
CLICK CHEMISTRY APPROACH
homogeneous catalysis
HUISGEN 1,3-DIPOLAR CYCLOADDITION
CONJUGATE ADDITION
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Summary:The use of commercially available azide sources is presented for the cobalt-catalyzed hydroazidation reaction alpha,alpha-Disubstituted olefins with a variety of functional groups were employed as substrates, providing tertiary azides in useful yields.
ISSN:0039-7881
DOI:10.1055/s-2007-1000817