Intercalation of lithium into porous titanium oxide produced by anodic oxidation

Process of lithium intercalation in a 1 M anhydrous propylene carbonate solution of LiClO 4 into porous titanium oxide produced by anodic oxidation of titanium in aqueous and nonaqueous electrolytes containing fluoride ions was studied. It is shown that the mass of intercalated lithium, which determ...

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Bibliographic Details
Published inRussian journal of applied chemistry Vol. 87; no. 2; pp. 184 - 189
Main Authors Maslov, V. V., Yurkinskii, V. P., Samsonova, I. A.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 2014
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Inorganic Synthesis and Industrial Inorganic Chemistry
Reversible Electrical Capacity
Lithium
Propylene Carbonate
Anodic Oxidation
Lithium Intercalation
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Summary:Process of lithium intercalation in a 1 M anhydrous propylene carbonate solution of LiClO 4 into porous titanium oxide produced by anodic oxidation of titanium in aqueous and nonaqueous electrolytes containing fluoride ions was studied. It is shown that the mass of intercalated lithium, which determines the efficiency of the cathodic reaction of lithium titanate formation, strongly depends on the specific surface area of the oxide. The results obtained make it possible to formulate approaches to solving the problem of raising the reversible electrical capacity of a lithium power source.
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427214020104