Synthesis of isoprenyl flavonoids: (+)-denticulaflavonol, macarangin, and isomacarangin

A straightforward synthesis of two natural C-alkylflavonoids: macarangin, isomacarangin, and the enantiomer of the natural (-)-denticulaflavonol, has been described.

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Bibliographic Details
Published inSynlett no. 8; pp. 1149 - 1152
Main Authors Basabe, Pilar, de Roman, Monica, Diez, David, Marcos, Isidro S., Bodero, Olga, Blanco, Araceli, Mollinedo, Faustino, Urones, Julio G.
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 05.05.2008
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
denticulaflavonol
isoprenyl flavonoids
antitumour activity
SCLAREOL
macarangin
BAKER-VENKATARAMAN REARRANGEMENT
isomacarangin
TERPENE
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Summary:A straightforward synthesis of two natural C-alkylflavonoids: macarangin, isomacarangin, and the enantiomer of the natural (-)-denticulaflavonol, has been described.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2008-1072734