Self-assembly of supramolecular Ni(II) and Cu(II) metalmacrocyclic compounds with tetraazamacrocyclic ligand into a gelatin-immobilized matrix

Self-assembly in M(II)-ethanedithioamide [H 2 N-C(=S)-C(=S)-NH 2 ]-propanone triple systems (M=Ni, Cu) into corresponding metal(II) hexacyanoferrate(II) gelatin-immobilized matrix systems under contact with aqueous-alkaline (pH ∼ 12) solutions containing ethanedithioamide and propanone have been stu...

Full description

Saved in:
Bibliographic Details
Published inJournal of coordination chemistry Vol. 63; no. 24; pp. 4309 - 4318
Main Authors Mikhailov, O.V., Chachkov, D.V.
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis Group 20.12.2010
Taylor & Francis Ltd
Subjects
Acetone
Coordination compounds
Copper
Gelatin
Gelatin-immobilized matrix
Molecular chains
Nickel compounds
Self-assembly
Supramolecular macrocyclic compound
Template synthesis
Online AccessGet full text

Cover

More Information
Summary:Self-assembly in M(II)-ethanedithioamide [H 2 N-C(=S)-C(=S)-NH 2 ]-propanone triple systems (M=Ni, Cu) into corresponding metal(II) hexacyanoferrate(II) gelatin-immobilized matrix systems under contact with aqueous-alkaline (pH ∼ 12) solutions containing ethanedithioamide and propanone have been studied. Formation of supramolecular macrotetracyclic compounds of Ni(II) and Cu(II) with 2,7,7,9,14,14-hexamethyl-3,6,10,13-tetraazacyclotetradecadien-2,9-tetrathione-4,5,11,12 containing original "kernel" (metal complex) and "shell" surrounding this "kernel", of polypeptide chains of the gelatin molecules, occurs under such specific conditions.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958972.2010.536536