Alternative Metal-Free Synthesis of Diorganoyl Selenides and Tellurides Mediated by Oxone (R)

We herein describe an alternative metal-free methodology for the synthesis of diorganyl selenides and tellurides mediated by Oxone (R). The products were obtained in moderate to excellent yields by reactions of diorganyl diselenides or ditellurides with aryl boronic acids mediated by Oxone (R) with...

Full description

Saved in:
Bibliographic Details
Published inSynlett Vol. 29; no. 11; pp. 1479 - 1484
Main Authors Perin, Gelson, Duarte, Luis Fernando B., Neto, Jose S. S., Silva, Marcio S., Alves, Diego
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 02.07.2018
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ANTIOXIDANT ACTIVITY
SELECTIVE OXIDATION
CATALYZED SYNTHESIS
UNSYMMETRICAL ORGANOCHALCOGENIDES
aryl boronic acids
green chemistry
Oxone (R)
ARYLBORONIC ACIDS
organoselenium compounds
CARBON-SELENIUM
COUPLING REACTIONS
DIPHENYL DISELENIDE
DIARYL DISELENIDES
diaryl selenides
Online AccessGet more information

Cover

More Information
Summary:We herein describe an alternative metal-free methodology for the synthesis of diorganyl selenides and tellurides mediated by Oxone (R). The products were obtained in moderate to excellent yields by reactions of diorganyl diselenides or ditellurides with aryl boronic acids mediated by Oxone (R) with use of EtOH as the solvent. The methodology is applicable to a broad scope of diorganyl dichalcogenides and aryl boronic acids containing electron-rich, electron-poor, and sterically hindered substituents.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-0036-1591992