Synthesis and Stille Cross-Coupling Reactions of 2-(Tributylstannyl)- and 2,5-Bis(trimethylstannyl)tellurophene

Herein, we describe the synthesis and Stille cross-coupling reactions of 2-(tributylstannyl)- and 2,5-bis(trimethylstannyl)tellurophene. The reactions were most optimal when using aryl iodides as coupling partners, and a mixed catalyst system consisting of tetrakis(triphenylphosphine)palladium(0) an...

Full description

Saved in:
Bibliographic Details
Published inSynthesis (Stuttgart) no. 19; pp. 3214 - 3218
Main Authors Sweat, Daniel P., Stephens, Chad E.
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.10.2009
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
IN-VITRO
cross-coupling
palladium
heterocyclic
AGENTS
tellurophene
Stille reaction
DERIVATIVES
FLUORIDE
Online AccessGet more information

Cover

More Information
Summary:Herein, we describe the synthesis and Stille cross-coupling reactions of 2-(tributylstannyl)- and 2,5-bis(trimethylstannyl)tellurophene. The reactions were most optimal when using aryl iodides as coupling partners, and a mixed catalyst system consisting of tetrakis(triphenylphosphine)palladium(0) and copper(I) iodide, together with cesium fluoride as additive, in N,N-dimethylformamide. This is the first reported synthesis and use of stannylated tellurophenes for cross-coupling reactions.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0029-1216958