Synthesis of Unsymmetrical Pyridyl Aryl Selenides by the Reductive Cleavage of Se─Se Bond
An efficient protocol for the synthesis of novel hitherto unknown substituted and unsubstituted phenyl pyridyl selenides from dipyridyl/diphenyl diselenides and phenyl/pyridyl halides in the presence of copper catalysed system, Cu 2 O/Mg/bpy is being presented. All the synthesized selenides are eith...
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Published in | Phosphorus, sulfur, and silicon and the related elements Vol. 183; no. 4; pp. 992 - 997 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
ABINGDON
Taylor & Francis Group
01.04.2008
Taylor & Francis |
Subjects | |
Online Access | Get full text |
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Summary: | An efficient protocol for the synthesis of novel hitherto unknown substituted and unsubstituted phenyl pyridyl selenides from dipyridyl/diphenyl diselenides and phenyl/pyridyl halides in the presence of copper catalysed system, Cu
2
O/Mg/bpy is being presented. All the synthesized selenides are either light yellow coloured liquids or low melting solids. All the newly synthesized compounds have been thoroughly characterized by elemental analysis employing various spectroscopic techniques viz., infrared, multinuclear NMR (
1
H,
13
C,
77
Se) and mass spectrometry (in representative cases). |
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ISSN: | 1042-6507 1563-5325 |
DOI: | 10.1080/10426500801900980 |