Advances in the selective functionalization of B(3,6)–H of o -carboranes

This review summarizes the methodologies for the selective functionalization of the B(3,6) vertices of o -carboranes, including the deboration-capitation reaction, the coupling reaction of B–X (X = I, Br) bonds, reactions of 1,3-dehydro- o -carborane and [3-N 2 - o -C 2 B 10 H 11 ][BF 4 ] as well as...

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Published inOrganic & biomolecular chemistry Vol. 23; no. 16; pp. 3701 - 3711
Main Authors Wu, Ji, Cao, Ke
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 16.04.2025
Subjects
Apexes
Carborane
Chemical reactions
Transition metals
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ISSN1477-0520
1477-0539
1477-0539
DOI10.1039/D4OB01778A

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Summary:This review summarizes the methodologies for the selective functionalization of the B(3,6) vertices of o -carboranes, including the deboration-capitation reaction, the coupling reaction of B–X (X = I, Br) bonds, reactions of 1,3-dehydro- o -carborane and [3-N 2 - o -C 2 B 10 H 11 ][BF 4 ] as well as transition-metal-catalyzed B–H activation. These works offer a versatile toolbox for synthesizing B(3,6)-substituted o -carborane derivatives and will promote their applications in material science, pharmaceutical chemistry, and related disciplines.
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ISSN:1477-0520
1477-0539
1477-0539
DOI:10.1039/D4OB01778A