A stereoselective Suzuki cross-coupling strategy for the synthesis of ethyl-substituted conjugated dienoic esters and conjugated dienones

A stereoselective approach towards ethyl-substituted conjugated dienoic esters and dienones utilising a Suzuki cross-coupling reaction has been achieved. In addition, a method for their conversion into the corresponding ethyl ketones is presented.

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Bibliographic Details
Published inSynlett no. 20; pp. 3457 - 3460
Main Authors Keck, Daniel, Muller, Thierry, Braese, Stefan
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 18.12.2006
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
dienoic esters
cross-coupling
triflate
stereoselective
PHOSPHORORGANISCHE VERBINDUNGEN
Suzuki reaction
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Summary:A stereoselective approach towards ethyl-substituted conjugated dienoic esters and dienones utilising a Suzuki cross-coupling reaction has been achieved. In addition, a method for their conversion into the corresponding ethyl ketones is presented.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2006-958406