Catalysts on functionalized polymer chips (PC) as recyclable entities

We describe surface-modified sintered polyethylene sheets as a suitable carrier system for various catalysts. The material shows high rigidity and no swelling properties and allows for easy removal and reuse of the supported catalysts. The application was demonstrated for Pd-, Rh-, and Ru-catalysts...

Full description

Saved in:
Bibliographic Details
Published inSynthesis (Stuttgart) no. 19; pp. 3362 - 3372
Main Authors Koc, F, Michalek, F, Rumi, L, Bannwarth, W, Haag, R
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.12.2005
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
olefin metathesis
heterogeneous catalysis
OLEFIN METATHESIS CATALYSTS
RUTHENIUM-CARBENE COMPLEX
SOL-GEL
solid support
RHODIUM-COMPLEXED DENDRIMERS
IMMOBILIZATION
ruthenium
LIGANDS
HYDROFORMYLATION REACTIONS
palladium
hydroformylation
IONIC LIQUIDS
EFFICIENT
PALLADIUM CATALYSTS
rhodium
Suzuki reaction
Online AccessGet more information

Cover

More Information
Summary:We describe surface-modified sintered polyethylene sheets as a suitable carrier system for various catalysts. The material shows high rigidity and no swelling properties and allows for easy removal and reuse of the supported catalysts. The application was demonstrated for Pd-, Rh-, and Ru-catalysts in Suzuki couplings, hydroformylation, and olefin metathesis, respectively.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2005-918479