Spin crossover {[Fe(atrz) 3 ](OTs) 2 } n monolith: a green synthesis approach for Robust switchable materials

This work presents a straightforward, room-temperature synthesis of a robust {[Fe(atrz) ](OTs) } monolith. This approach offers a green alternative to traditional nanoparticle synthesis for manipulating spin crossover (SCO) behaviour. The monolith exhibits a more gradual SCO transition at lower temp...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 53; no. 22; pp. 9257 - 9261
Main Authors Martinez-Martinez, Ana, Albacete, Pablo, García-Hernández, Mar, Resines-Urien, Esther, Fairen-Jimenez, David, Sánchez Costa, José
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2024
Subjects
Crossovers
Robustness
Room temperature
Synthesis
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Summary:This work presents a straightforward, room-temperature synthesis of a robust {[Fe(atrz) ](OTs) } monolith. This approach offers a green alternative to traditional nanoparticle synthesis for manipulating spin crossover (SCO) behaviour. The monolith exhibits a more gradual SCO transition at lower temperatures compared to the bulk material, aligning with observations in smaller particle systems. Notably, the synthesis employs a solvent- and surfactant-free approach, simplifying the process and potentially reducing environmental impact, aligning with the principles of green chemistry.
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ISSN:1477-9226
1477-9234
DOI:10.1039/d4dt00684d