Formal total synthesis of (+/-)-herbertene-1,13-diol and (+/-)-alpha-herbertenol via Ireland ester Claisen rearrangement and RCM reaction sequence
A combination of Ireland ester Claisen rearrangement and ring-closing metathesis (RCM) reactions has been employed for efficient formal total syntheses of herbertene-1,13-diol and alpha-herbertenol, sesquiterpenes containing two vicinal quaternary carbon atoms on a cyclopentane ring.
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Published in | Synlett no. 7; pp. 1173 - 1175 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
STUTTGART
Thieme Medical Publishers
02.05.2005
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Subjects | |
Online Access | Get more information |
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Summary: | A combination of Ireland ester Claisen rearrangement and ring-closing metathesis (RCM) reactions has been employed for efficient formal total syntheses of herbertene-1,13-diol and alpha-herbertenol, sesquiterpenes containing two vicinal quaternary carbon atoms on a cyclopentane ring. |
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ISSN: | 0936-5214 1437-2096 |
DOI: | 10.1055/s-2005-865223 |