Polymorphism and Mixing Phase Behavior in Ternary Mixture Systems of SOS–SSO–OSO: Formation of Molecular Compound Crystals

• Published in: Journal of the American Oil Chemists' Society Vol. 95; no. 4; pp. 447 - 460
• Main Authors: Watanabe, Shimpei, Yoshikawa, Shinichi, Arishima, Toshiharu, Sato, Kiyotaka
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 01.04.2018
• Subjects: Molecular compound; Polymorphism; Ternary phase behavior; Triacylglycerol
• ISSN: 0003-021X; 1558-9331
• DOI: 10.1002/aocs.12054

This paper reports the phase behavior of ternary mixtures of saturated and cis‐monounsaturated mixed‐acid triacylglycerols (TAG) of SOS (1,3‐distearoyl‐2‐oleoyl‐glycerol), SSO (1,2‐distearoyl‐3‐oleoyl‐rac‐glycerol), and OSO (1,3‐dioleoyl‐2‐stearoyl‐glycerol) examined with X‐ray diffractometry and a differential scanning calorimeter. The ternary mixtures were crystallized by cooling from melt (60 °C) to 5 °C, and the crystals were then stabilized by storing the mixture samples at 28 °C for 10 days. The following results were obtained. (1) Molecular compound (MC) crystals of stable β polymorph having a double‐chain‐length structure (β‐2) were formed in mixtures of SOS/SSO/OSO in which the concentration of SOS was 50% with varying concentrations of SSO/OSO. This is in contrast to the fact that the stable polymorphic forms of the component TAG are β‐3 for SOS and OSO and β′‐3 for SSO. (2) When the concentration of SOS deviated from 50%, immiscible mixtures of β‐2 MC made of SOS/SSO/OSO and the component TAG (β‐3 of SOS and OSO and β′‐3 of SSO) were formed. Therefore, ternary mixtures of SOS/(SSO + OSO) = 50/50 with different concentrations of SSO and OSO are miscible mixtures of β‐2 of SOS/SSO and SOS/OSO.