PHENYLATION OF ALKENYL TRIFLATES - REACTION WITH TETRABUTYLAMMONIUM DIFLUOROTRIPHENYLSTANNATE

The reaction of alkenyl triflates 1 with tetrabutylammonium difluorotriphenylstannate catalyzed by Pd(PPh(3))(4) affords regio and stereospecifically the corresponding alkenylbenzenes 2 in excellent yields.

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Bibliographic Details
Published inSynlett no. 12; pp. 1047 - 1048
Main Authors MARTINEZ, AG, BARCINA, JO, CEREZO, AD, SUBRAMANIAN, LR
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.12.1994
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
VINYL
CEPHALOSPORIN CHEMISTRY
ARYLSTANNANES
PALLADIUM CATALYSIS
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Summary:The reaction of alkenyl triflates 1 with tetrabutylammonium difluorotriphenylstannate catalyzed by Pd(PPh(3))(4) affords regio and stereospecifically the corresponding alkenylbenzenes 2 in excellent yields.
ISSN:0936-5214
DOI:10.1055/s-1994-23081