Relationship of Strength of Fibers Obtained from Ultrahigh-Molecular-Weight Polyethylene Gel with Different Multiplicity of Orientation Stretching with their Breaking Elongation

• Published in: Fibre chemistry Vol. 55; no. 5; pp. 286 - 289
• Main Authors: Galitsyn, V. P., Shkurenko, S. I., Sokolov, A. V., Pakhomov, P. M.
• Format: Journal Article
• Language: English
• Published: New York Springer US 2024; Springer Nature B.V
• Subjects: Chemistry; Chemistry and Materials Science; Elongation; Mechanical properties; Organic Chemistry; Polymer Sciences; Straight lines; Stretching; Ultra high molecular weight polyethylene
• ISSN: 0015-0541; 1573-8493
• DOI: 10.1007/s10692-024-10478-2

The object of the study were samples of fibers obtained from ultrahigh-molecular-weight polyethylene (UHMWP) gel with different multiplicity of stretching (λ) with a scatter (dispersion) of mechanical properties. It is shown that the dependence of strength (σ b ) on breaking elongation (ε) of the studied samples is expressed by the equation σ b = σ b0 + K ·ε and appears as a series of variously inclined straight lines specific for each λ value, which converge upon extrapolation to ε = 0 to a single point (pole), the ordinate of which coincides with the strength of unoriented fiber (σ b0 ). With increase of λ the straight lines representing the course of the relationships σ b (ε) shift toward low ε values. The decrease of ε is compensated abundantly by increase of angular coefficient K , which determines the degree of effect of ε on σ b .