A green, ionic liquid and quaternary ammonium salt-catalyzed aza-Michael reaction of α,β-ethylenic compounds with amines in water

The first environmentally benign, highly efficient conjugate addition of aliphatic amines to alpha,beta-unsaturated compounds catalysed by simple quaternary ammonium salts and ionic liquids in the green solvent, water, is described.

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Bibliographic Details
Published inNew journal of chemistry Vol. 28; no. 2; pp. 183 - 184
Main Authors Xu, Li-Wen, Li, Jing-Wei, Zhou, Shao-Lin, Xia, Chun-Gu
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 2004
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
FACILE SYNTHESIS
ENANTIOSELECTIVE SYNTHESIS
IMINES
ORGANIC-REACTIONS
ENONES
ALIPHATIC-AMINES
ASYMMETRIC SYNTHESES
EFFICIENT
EPOXIDATION
CONJUGATE ADDITION
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Summary:The first environmentally benign, highly efficient conjugate addition of aliphatic amines to alpha,beta-unsaturated compounds catalysed by simple quaternary ammonium salts and ionic liquids in the green solvent, water, is described.
ISSN:1144-0546
1369-9261
DOI:10.1039/B312047C