Regioselective Synthesis of 5-(2-Cyanoethyl)-1,1′-biphenyl-2-carboxylates by Formal [3+3] Cyclocondensations of 1,3-Bis[(trimethylsilyl)oxy]buta- 1,3-dienes

• Published in: Helvetica chimica acta Vol. 96; no. 12; pp. 2185 - 2190
• Main Authors: Bendrath, Franziska, Abilov, Zharylkasyn A., Falodun, Abiodun, Hein, Martin, Villinger, Alexander, Langer, Peter
• Format: Journal Article
• Language: English
• Published: Zürich WILEY-VCH Verlag 01.12.2013; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: 1,1′‐Biphenyl‐2‐carboxylates, 5‐(2‐cyanoethyl); 1′-Biphenyl-2-carboxylates; 5-(2-cyanoethyl); Cyclization reactions; Silyl enol ethers
• ISSN: 0018-019X; 1522-2675
• DOI: 10.1002/hlca.201200615

5‐(2‐Cyanoethyl)‐1,1′‐biphenyl‐2‐carboxylates were prepared by regioselective formal [3+3] cyclocondensations of 1,3‐bis[(trimethylsilyl)oxy]buta‐1,3‐dienes.