A convenient access to perfluoroalkyl selenoethers and selenyl chlorides

The treatment of diselenides with different perfluoroalkyl iodides in the presence of sodium hydroxymethanesulfinate led to perfluoroalkyl selenides in fair to good yields. The reaction between benzyl perfluorooctyl selenide and chlorine. or sulfuryl chloride. gave rise to the corresponding selenyl...

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Bibliographic Details
Published inSynlett no. 8; pp. 1260 - 1262
Main Authors Magnier, E, Vit, E, Wakselman, C
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 2001
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Summary:The treatment of diselenides with different perfluoroalkyl iodides in the presence of sodium hydroxymethanesulfinate led to perfluoroalkyl selenides in fair to good yields. The reaction between benzyl perfluorooctyl selenide and chlorine. or sulfuryl chloride. gave rise to the corresponding selenyl chloride and represents an easy route to perfluoroalkylselenyl chlorides.
ISSN:0936-5214
DOI:10.1055/s-2001-16050