Two-photon, red light uncaging of alkyl radicals from organorhodium() phthalocyanine complexes

A stepwise two-photon, red light excitation of organorhodium( iii ) phthalocyanine complexes was found to induce the activation of the axial metal-carbon bond to generate alkyl radicals/aldehydes. The cooperative action of the photouncaging reaction and the photochemical generation of reactive oxyge...

Full description

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 58; no. 8; pp. 1128 - 11283
Main Authors Murata, Kei, Saibe, Yuki, Uchida, Mayu, Aono, Mizuki, Misawa, Ryuji, Ikeuchi, Yoshiho, Ishii, Kazuyuki
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 06.10.2022
Subjects
Aldehydes
Photochemical reactions
Photons
Online AccessGet full text

Cover

More Information
Summary:A stepwise two-photon, red light excitation of organorhodium( iii ) phthalocyanine complexes was found to induce the activation of the axial metal-carbon bond to generate alkyl radicals/aldehydes. The cooperative action of the photouncaging reaction and the photochemical generation of reactive oxygen species were indicated to induce the cell deaths. The photouncaging reaction of alkyl radicals from the organorhodium( iii ) phthalocyanine complexes was achieved by a stepwise two-photon, red light excitation.
Bibliography:https://doi.org/10.1039/d2cc03672j
Electronic supplementary information (ESI) available. See DOI
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc03672j