Efficient copper-catalyzed chemo selective conjugate addition of aliphatic amines to alpha,beta-unsaturated compounds in water

The first environmentally benign, highly efficient, conjugate addition of aliphatic amines to alpha,beta-unsaturated compounds catalyzed by simple copper salts in the green solvent, water is described.

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Bibliographic Details
Published inSynlett no. 15; pp. 2425 - 2427
Main Authors Xu, LW, Li, JW, Xia, CG, Zhou, SL, Hu, XX
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.12.2003
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ASYMMETRIC-SYNTHESIS
alpha,beta-unsaturated compounds
ENANTIOSELECTIVE SYNTHESIS
ORGANIC-REACTIONS
amines
MICHAEL-TYPE ADDITION
CARBONYL-COMPOUNDS
HYDROAMINATION
conjugate addition
water
ALCOHOLS
ACID-DERIVATIVES
METALS
copper
STEREOSELECTIVE-SYNTHESIS
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Summary:The first environmentally benign, highly efficient, conjugate addition of aliphatic amines to alpha,beta-unsaturated compounds catalyzed by simple copper salts in the green solvent, water is described.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2003-42125