Fabrication of Cu2+ substituted nanocrystalline Ni–Zn ferrite by solution combustion route: Investigations on structure, cation occupancy and magnetic behavior

• Published in: Journal of alloys and compounds Vol. 553; pp. 157 - 162
• Main Authors: Awati, V.V., Rathod, S.M., Shirsath, Sagar E., Mane, Maheshkumar L.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 15.03.2013; Elsevier
• Subjects: Annealing treatment; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Crystal structure; Exact sciences and technology; Ferrite; Magnetic properties and materials; Magnetic properties of nanostructures; Materials science; Methods of nanofabrication; Morphology; Nanocrystalline materials; Nanoscale materials and structures: fabrication and characterization; Nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals; Physics; Structure of solids and liquids; crystallography; Ferrite; Annealing treatment; Morphology; Crystal structure; Scanning electron microscopy; Cubic lattices; Combustion synthesis; Annealing; Crystallinity; XRD; Field emission electron microscopy; Ferrites spinels; Spinels; Chemical composition; Fourier-transformed infrared spectrometry; Nanocrystal; Nanomaterial synthesis; Saturation magnetization; Copper Iron Nickel Zinc Oxides Mixed
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2012.11.045

► Synthesis of ferrite by solution combustion route. ► Characterization techniques XRD, SEM, magnetization. ► Structural properties. ► Cation distribution. ► Magnetic properties. The reactivity of Cu2+ ion concentration in Ni–Zn spinel matrix fabricated using solution combustion route has been investigated. The specimens of nanocrystalline Ni0.8−xCuxZn0.2Fe2O4 (x=0.0⩽0.6 with steps of 0.2) exhibits single phase cubic structure. The detailed studies regarding the physico-chemical stability, crystal structural stability, surface morphology and magnetic properties as a function of Cu2+ ion concentration were performed. The annealing treatment does not alter the crystal structure but increases the crystallinity of the samples. The cation occupancies of the prepared materials were estimated by using X-ray diffraction (XRD) data analysis. The morphological investigations of the samples were studied by using field emission scanning electron microscopy (FE-SEM) technique. The crystallographic analyses of all the compositions were systematically investigated by Fourier transform infrared spectroscopy (FTIR). The saturation magnetization (M–H plots) at room temperature with field 10kOe exhibits strong influence of Cu2+ ion content and annealing temperature.