Assisted assembling of Bi2WO6/rGO composites: A 3D/2D Hierarchical nanostructures for enhanced photocatalytic water remediation and photo-(electro)catalytic water splitting proficiency

• Published in: Chemosphere (Oxford) Vol. 345; p. 140488
• Main Authors: K, Annamalai, Natarajan, Sasirekha, S, Balakumar
• Format: Journal Article
• Language: English
• Published: 01.12.2023
• ISSN: 0045-6535; 1879-1298; 1879-1298
• DOI: 10.1016/j.chemosphere.2023.140488

The current study explores the possibility of effectively improving Bi2WO6 (BWO) nanostructures in photocatalytic clean H2 generation and treating water from pharmaceutical wastes. BWO nanoparticles (NPs) hybridized with carbon-derived materials proved to be an efficient candidate in the field of photocatalysis. In this work, BWO nanostructures have been synthesized via the facile co-precipitation technique. The reduced graphene oxide (r-GO) was used as the carbon derivative for the hybridization process. Furthermore, different weight percentages of rGO were loaded with BWO NPs through the wet impregnation technique. The structural, and morphological analysis confirmed the formation of BWO/x% rGO composites. UV-DRS analysis showcased the reduction in bandgap in annexure with increased light absorbance region upon rGO inclusion. Time-resolved photoluminescence (TRPL) proved a prolonged lifetime for BWO/15% rGO composite. In addition, their photocatalytic abilities were put to the test, and BWO/15% rGO nano-hybrid demonstrated a superior degradation of pharmaceutical wastes like tetracycline hydrochloride (TCH) and levofloxacin (LVX) from water in 15 min. Furthermore, photo-electrochemical measurements showed the lowest onset potential and better charge transfer for efficient splitting of water. The photocatalytic water splitting was performed in the presence of sacrificial agents and in the absence of sacrificial agents, where BWO/15% rGO exhibited maximum H2 evolution.The current study explores the possibility of effectively improving Bi2WO6 (BWO) nanostructures in photocatalytic clean H2 generation and treating water from pharmaceutical wastes. BWO nanoparticles (NPs) hybridized with carbon-derived materials proved to be an efficient candidate in the field of photocatalysis. In this work, BWO nanostructures have been synthesized via the facile co-precipitation technique. The reduced graphene oxide (r-GO) was used as the carbon derivative for the hybridization process. Furthermore, different weight percentages of rGO were loaded with BWO NPs through the wet impregnation technique. The structural, and morphological analysis confirmed the formation of BWO/x% rGO composites. UV-DRS analysis showcased the reduction in bandgap in annexure with increased light absorbance region upon rGO inclusion. Time-resolved photoluminescence (TRPL) proved a prolonged lifetime for BWO/15% rGO composite. In addition, their photocatalytic abilities were put to the test, and BWO/15% rGO nano-hybrid demonstrated a superior degradation of pharmaceutical wastes like tetracycline hydrochloride (TCH) and levofloxacin (LVX) from water in 15 min. Furthermore, photo-electrochemical measurements showed the lowest onset potential and better charge transfer for efficient splitting of water. The photocatalytic water splitting was performed in the presence of sacrificial agents and in the absence of sacrificial agents, where BWO/15% rGO exhibited maximum H2 evolution.