Study on the synthesis of 1,3,5-triazinane derivatives on copper-ferrite nanoparticles catalyst

Abstract A high efficient method for the synthesis of 1,3,5-triaryltriazinane derivatives is developed by the condensation reaction of amines and formaldehyde followed by spontaneous cyclotrimerization using CuFe 2 O 4 NPs as an environmentally benign catalyst at room temperature. The copper ferrite...

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Published inIOP conference series. Earth and environmental science Vol. 947; no. 1; pp. 12028 - 12036
Main Authors Pham, Thao Xuan, Pham, Minh Tuan, Cao, Hai Thuong, Nguyen, Bich Ngoc, Nguyen, Quang Ha, Trang, Bui Thuy
Format Journal Article
LanguageEnglish
Published Bristol IOP Publishing 01.12.2021
Subjects
Amines
Catalysts
Copper
Copper ferrite
Nanoparticles
Room temperature
Selectivity
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Summary:Abstract A high efficient method for the synthesis of 1,3,5-triaryltriazinane derivatives is developed by the condensation reaction of amines and formaldehyde followed by spontaneous cyclotrimerization using CuFe 2 O 4 NPs as an environmentally benign catalyst at room temperature. The copper ferrite was easily separated, reused in good repetitive catalytic performance by simple filtration or external magnet. This process was efficient and compatible with wide range of amines to afford a direct access to nitrogen containing compounds in excellent yields up to 99% and high selectivity.
ISSN:1755-1307
1755-1315
DOI:10.1088/1755-1315/947/1/012028