On the Influence of Kinetic Uncertainties on the Accuracy of Numerical Modeling of an Industrial Flameless Furnace Fired With NH3/H2 Blends: A Numerical and Experimental Study

• Published in: Frontiers in energy research Vol. 8
• Main Authors: Ferrarotti, Marco, Bertolino, Andrea, Amaduzzi, Ruggero, Parente, Alessandro
• Format: Journal Article
• Language: English
• Published: Frontiers Media S.A 17.12.2020
• Subjects: ammonia; flameless; hydrogen; partially stirred reactor; uncertainty propagation
• ISSN: 2296-598X; 2296-598X
• DOI: 10.3389/fenrg.2020.597655

Ammonia/hydrogen-fueled combustion represents a very promising solution for the future energy scenario. This study aims to shed light and understand the behavior of ammonia/hydrogen blends under flameless conditions. A first-of-its-kind experimental campaign was conducted to test fuel flexibility for different ammonia/hydrogen blends in a flameless burner, varying the air injector and the equivalence ratio. NO emissions increased drastically after injecting a small amount of NH 3 in pure hydrogen (10% by volume). An optimum trade-off between NOx emission and ammonia slip was found when working sufficiently close to stoichiometric conditions ( ϕ = 0.95). In general, a larger air injector (ID25) reduces the emissions, especially at ϕ = 0.8. A well-stirred reactor network with exhaust recirculation was developed exchanging information with computational fluid dynamics (CFD) simulations, to model chemistry in diluted conditions. Such a simplified system was then used in two ways: 1) to explain the experimental trends of NOx emissions varying the ammonia molar fraction within the fuel blend and 2) to perform an uncertainty quantification study. A sensitivity study coupled with latin hypercube sampling (LHS) was used to evaluate the impact of kinetic uncertainties on NOx prediction in a well-stirred reactor network model. The influence of the identified uncertainties was then tested in more complex numerical models, such as Reynolds-averaged Navier–Stokes (RANS) simulations of the furnace. The major over-predictions of existing kinetic scheme was then alleviated significantly, confirming the crucial role of detailed kinetic mechanisms for accurate predictive simulations of NH 3 /H 2 mixtures in flameless regime.