OXIDATIVE DECARBOXYLATION OF ALPHA-AMINO-ACIDS WITH IN-SITU GENERATED DIMETHYL DIOXIRANE

Oxidative decarboxylation of alpha-amino acids with acetone-potassium peroxymonosulfate (oxone(R)) is described. The reaction represents the first example of oxidative decarboxylation of an alpha-amino acid RCH(NH2)COOH in which a product other than an aldehyde RCHO or a carboxylic acid RCOOH has be...

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Bibliographic Details
Published inSynlett no. 10; pp. 1059 - 1058
Main Authors PARADKAR, VM, LATHAM, TB, DEMKO, DM
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.10.1995
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
OXONE(R)
OXIDATIVE DECARBOXYLATION
DIMETHYL DIOXIRANE
ALPHA-AMINO ACIDS
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Summary:Oxidative decarboxylation of alpha-amino acids with acetone-potassium peroxymonosulfate (oxone(R)) is described. The reaction represents the first example of oxidative decarboxylation of an alpha-amino acid RCH(NH2)COOH in which a product other than an aldehyde RCHO or a carboxylic acid RCOOH has been isolated as the major component.
ISSN:0936-5214
DOI:10.1055/s-1995-5174