Enhanced C3H6/C3H8 separation performance in polysulfone membrane blended with rigid ZIF-8 crystals

• Published in: Frontiers of chemical science and engineering Vol. 19; no. 1
• Main Authors: Luo, Jiayu, Lyu, Luxi, Yin, Zongjie, Wei, Yanying
• Format: Journal Article
• Language: English
• Published: Beijing Higher Education Press 01.01.2025; Springer Nature B.V
• Subjects: Chemistry; Chemistry and Materials Science; Electric fields; Flexible structures; Industrial Chemistry/Chemical Engineering; Membranes; Metal-organic frameworks; Nanotechnology; Outstanding young chemical engineers and the future chemical engineers; Permeability; Polysulfone resins; Pressure dependence; Research Article; Separation; Zeolites; gas separation; mixed matrix membranes; metal-organic frameworks
• ISSN: 2095-0179; 2095-0187
• DOI: 10.1007/s11705-024-2504-3

Metal-organic frameworks have a wide range of applications in the field of membrane separation, but the inherent flexible structure and the difficulty for scale-up hinder their further applications. Herein, the relatively rigid zeolitic imidazolate framework-8 particles prepared under an electric field (E-ZIF-8) were used as the fillers in polysulfone (PSF) to form series of mixed matrix membranes. It was found that the introduction of E-ZIF-8 improves both the C 3 H 6 permeability and C 3 H 6 /C 3 H 8 selectivity of the membranes. Compared with the bare PSF membrane, the C 3 H 6 /C 3 H 8 selectivity of the 30 wt % E-ZIF-8@PSF membrane increased by ∼230%, while the C 3 H 6 permeability was enhanced by ∼830%. In addition, time and pressure dependence analysis demonstrated that such E-ZIF-8@PSF membranes also exhibited good long-term stability and pressure resistance, offering significant industrialization advantages.