Reactions of UF6 and HF with Ethanol

Qualitative studies were performed, and the feasibility of ethanol fluorination by its reactions with anhydrous HF and UF 6 was demonstrated. The reaction occurs at temperatures of up to 150°С via replacement of OH groups with probable formation of Freon 161 and substitution of СH groups with the mo...

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Published inRadiochemistry (New York, N.Y.) Vol. 60; no. 2; pp. 152 - 157
Main Authors Gromov, O. B., Khorozova, O. D., Travin, S. O., Atakhanova, E. L.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.03.2018
Springer Nature B.V
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Ethanol
Feasibility studies
Fluorides
Fluorination
Freons
Infrared spectroscopy
Nuclear Chemistry
Reaction products
Substitution reactions
Uranium
Uranium fluorides
Freons
IR spectrometry
ethanol
hydrogen fluoride
qualitative analysis
uranium hexafluoride
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Summary:Qualitative studies were performed, and the feasibility of ethanol fluorination by its reactions with anhydrous HF and UF 6 was demonstrated. The reaction occurs at temperatures of up to 150°С via replacement of OH groups with probable formation of Freon 161 and substitution of СH groups with the most probable formation of Freon 152. The Freons were identified by IR spectroscopy. The solid reaction products mainly consist of intermediate uranium fluorides. The formation of uranyl fluoride is not proved unambiguously.
ISSN:1066-3622
1608-3288
DOI:10.1134/S1066362218020042