Formation of C=N bonds by the release of H2: a new strategy for synthesis of imines and benzazoles

A new strategy for synthesis of imines using the approach of release of H2 has been developed. This oxidant- and acceptor-free Pd/C catalysis protocol is further applied to synthesis of benzoxazoles, benzimidazoles, and benzothiazoles through a one-pot cascade reaction with notably high yields.

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Bibliographic Details
Published inOrganic & biomolecular chemistry Vol. 11; no. 23; pp. 3776 - 3780
Main Authors Jin, Xukang, Liu, Yuxiao, Lu, Qiongqiong, Yang, Dejun, Sun, Jiangkai, Qin, Shuangshuang, Zhang, Jingwu, Shen, Jiaxuan, Chu, Changhu, Liu, Renhua
Format Journal Article
LanguageEnglish
Published England 2013
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Summary:A new strategy for synthesis of imines using the approach of release of H2 has been developed. This oxidant- and acceptor-free Pd/C catalysis protocol is further applied to synthesis of benzoxazoles, benzimidazoles, and benzothiazoles through a one-pot cascade reaction with notably high yields.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1477-0520
1477-0539
DOI:10.1039/c3ob40388b